The publications of the members of the research group.
2023
Raffaele Mancino; Diego Caccavo; Anna Angela Barba; Gaetano Lamberti; Alice Biasin; Angelo Cortesi; Gabriele Grassi; Mario Grassi; Michela Abrami
Agarose Cryogels: Production Process Modeling and Structural Characterization Journal Article
In: Gels, vol. 9, no. 9, pp. 765, 2023, ISSN: 23102861.
Abstract | Links | BibTeX | Tags: Agarose, cryogels, Equilibrium, Hydrogels, Modeling, Rheology
@article{Mancino2023,
title = {Agarose Cryogels: Production Process Modeling and Structural Characterization },
author = {Raffaele Mancino and Diego Caccavo and Anna Angela Barba and Gaetano Lamberti and Alice Biasin and Angelo Cortesi and Gabriele Grassi and Mario Grassi and Michela Abrami},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-85172281028\&doi=10.3390%2fgels9090765\&partnerID=40\&md5=7753d30977c1b97694c4ede138749d57},
doi = {10.3390/gels9090765},
issn = {23102861},
year = {2023},
date = {2023-09-20},
journal = {Gels},
volume = {9},
number = {9},
pages = {765},
abstract = {A cryogel is a cross-linked polymer network with different properties that are determined by its manufacturing technique. The formation of a cryogel occurs at low temperatures and results in a porous structure whose pore size is affected by thermal conditions. The adjustable pore sizes of cryogels make them attractive for diverse applications. In this study, the influence of the external operational temperature, which affects the cooling and freezing rates, on the production of cryogels with 2% w/w agarose is investigated. Moreover, a mathematical model is developed to simulate the cryogel production process and provide an initial estimate of the pore size within the structure. The predictions of the model, supported by qualitative light microscopy images, demonstrate that cryogels produced at higher process temperatures exhibit larger pore sizes. Moreover, the existence of pore size distribution within the gel structure is confirmed. Finally, stress relaxation tests, coupled with an image analysis, validates that cryogels produced at lower temperatures possess a higher stiffness and slower water release rates.},
keywords = {Agarose, cryogels, Equilibrium, Hydrogels, Modeling, Rheology},
pubstate = {published},
tppubtype = {article}
}
A cryogel is a cross-linked polymer network with different properties that are determined by its manufacturing technique. The formation of a cryogel occurs at low temperatures and results in a porous structure whose pore size is affected by thermal conditions. The adjustable pore sizes of cryogels make them attractive for diverse applications. In this study, the influence of the external operational temperature, which affects the cooling and freezing rates, on the production of cryogels with 2% w/w agarose is investigated. Moreover, a mathematical model is developed to simulate the cryogel production process and provide an initial estimate of the pore size within the structure. The predictions of the model, supported by qualitative light microscopy images, demonstrate that cryogels produced at higher process temperatures exhibit larger pore sizes. Moreover, the existence of pore size distribution within the gel structure is confirmed. Finally, stress relaxation tests, coupled with an image analysis, validates that cryogels produced at lower temperatures possess a higher stiffness and slower water release rates.
2021
Diego Caccavo; Rosario Cavallo; Michela Abrami; Mario Grassi; Anna Angela Barba; Gaetano Lamberti
Dynamometric measurements of hydrogels' mechanical spectra Journal Article
In: Journal of Applied Polymer Science, vol. 138, no. 50702, 2021.
Abstract | Links | BibTeX | Tags: Gels, Rheology, Viscosity and Viscoelasticity
@article{Caccavo2021,
title = {Dynamometric measurements of hydrogels' mechanical spectra},
author = {Diego Caccavo and Rosario Cavallo and Michela Abrami and Mario Grassi and Anna Angela Barba and Gaetano Lamberti},
url = {https://onlinelibrary.wiley.com/doi/full/10.1002/app.50702},
doi = {10.1002/app.50702},
year = {2021},
date = {2021-03-12},
journal = {Journal of Applied Polymer Science},
volume = {138},
number = {50702},
abstract = {Hydrogels' viscoelastic behavior is crucial in several applications and an in‐depth knowledge and characterization of this property is essential to select the most appropriate gel for the specific use. Oscillatory shear measurements are the most commonly used techniques to perform the viscoelastic characterization of hydrogels, among other materials, and it is performed mainly by using plate‐plate shear rheometers. Despite these instruments constitute one of the best options to analyze the mechanical response of materials, they are quite expensive and require well trained operators, which confine their presence exclusively in engineering labs. However, the use of hydrogels brought these materials to be present in countless sectors, and therefore poses the need of reliable characterization with as much simple and common instrumentations. Therefore, aim of this work is to present the possibility to obtain a trustworthy characterization of the viscoelasticity of hydrogel by using a Texture Analyzer set to work with sinusoidal deformations.},
keywords = {Gels, Rheology, Viscosity and Viscoelasticity},
pubstate = {published},
tppubtype = {article}
}
Hydrogels' viscoelastic behavior is crucial in several applications and an in‐depth knowledge and characterization of this property is essential to select the most appropriate gel for the specific use. Oscillatory shear measurements are the most commonly used techniques to perform the viscoelastic characterization of hydrogels, among other materials, and it is performed mainly by using plate‐plate shear rheometers. Despite these instruments constitute one of the best options to analyze the mechanical response of materials, they are quite expensive and require well trained operators, which confine their presence exclusively in engineering labs. However, the use of hydrogels brought these materials to be present in countless sectors, and therefore poses the need of reliable characterization with as much simple and common instrumentations. Therefore, aim of this work is to present the possibility to obtain a trustworthy characterization of the viscoelasticity of hydrogel by using a Texture Analyzer set to work with sinusoidal deformations.